{"id":176,"date":"2024-08-06T01:56:55","date_gmt":"2024-08-06T01:56:55","guid":{"rendered":"https:\/\/chemneo.com\/?post_type=product&p=176"},"modified":"2024-08-06T01:57:24","modified_gmt":"2024-08-06T01:57:24","slug":"methylcyclopentadienyl-manganese-tricarbonyl-cas12108-13-3","status":"publish","type":"product","link":"https:\/\/chemneo.com\/pt\/product\/176.html","title":{"rendered":"Tricarbonilo de metilciclopentadienilo e mangan\u00eas CAS#12108-13-3"},"content":{"rendered":"
\n\n\n\n
Methylcyclopentadienyl manganese tricarbonyl Chemical Properties<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
Melting point<\/td>\n-1 \u00b0C (lit.)<\/span><\/td>\n<\/tr>\n
Ponto de ebuli\u00e7\u00e3o<\/td>\n232-233 \u00b0C (lit.)<\/span><\/td>\n<\/tr>\n
densidade<\/td>\n1.38 g\/mL at 25 \u00b0C (lit.)<\/span><\/td>\n<\/tr>\n
vapor density<\/td>\n>1 (vs air)<\/span><\/td>\n<\/tr>\n
vapor pressure<\/td>\n0.05 mm Hg ( 20 \u00b0C)<\/span><\/td>\n<\/tr>\n
\u00edndice de refra\u00e7\u00e3o<\/td>\nn<\/i>20\/D 1.584(lit.)<\/span><\/td>\n<\/tr>\n
Fp<\/td>\n205\u00a0\u00b0F<\/span><\/td>\n<\/tr>\n
storage temp.<\/td>\nPoison room<\/span><\/td>\n<\/tr>\n
forma<\/td>\nliquid<\/span><\/td>\n<\/tr>\n
color<\/td>\nyellow<\/span><\/td>\n<\/tr>\n
Gravidade espec\u00edfica<\/td>\n1.388<\/span><\/td>\n<\/tr>\n
Water Solubility<\/td>\nInsoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone<\/span><\/td>\n<\/tr>\n
Sensitive<\/td>\nAir Sensitive<\/span><\/td>\n<\/tr>\n
Merck<\/td>\n14,6223<\/span><\/td>\n<\/tr>\n
Exposure limits<\/td>\nACGIH: TWA 0.2 mg\/m3 (Skin)
\nOSHA: Ceiling 5 mg\/m3
\nNIOSH: IDLH 500 mg\/m3; TWA 0.2 mg\/m3; TWA 1 mg\/m3; STEL 3 mg\/m3<\/span><\/td>\n<\/tr>\n
Estabilidade:<\/td>\nStable. Incompatible with strong oxidizing agents.<\/span><\/td>\n<\/tr>\n
InChIKey<\/td>\nLYHJNAIHGFWRKM-UHFFFAOYSA-N<\/span><\/td>\n<\/tr>\n
LogP<\/td>\n3.4 at 26\u2103<\/span><\/td>\n<\/tr>\n
CAS DataBase Reference<\/td>\n12108-13-3(CAS DataBase Reference)<\/a><\/span><\/td>\n<\/tr>\n
Sistema de Registo de Subst\u00e2ncias da EPA<\/td>\nMethylcyclopentadienyl manganese tricarbonyl (12108-13-3)<\/a><\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>\n
\n\n\n\n\n
<\/td>\n<\/tr>\n
Informa\u00e7\u00f5es de seguran\u00e7a<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n\n
Hazard Codes<\/td>\nT,N,T+<\/a><\/span><\/td>\n<\/tr>\n
Risk Statements<\/td>\n23\/24\/25-40-50\/53-48\/23-38-26-24\/25<\/a><\/span><\/td>\n<\/tr>\n
Safety Statements<\/td>\n23-26-36\/37\/39-45-61-60-36\/37-28<\/a><\/span><\/td>\n<\/tr>\n
RIDADR<\/td>\nUN 3281 6.1\/PG 2<\/span><\/td>\n<\/tr>\n
OEB<\/td>\nC<\/span><\/td>\n<\/tr>\n
OEL<\/td>\nTWA: 0.2 mg\/m3 [skin]<\/span><\/td>\n<\/tr>\n
WGK Germany<\/td>\n3<\/span><\/td>\n<\/tr>\n
RTECS<\/td>\nOP1450000<\/span><\/td>\n<\/tr>\n
TSCA<\/td>\nYes<\/span><\/td>\n<\/tr>\n
HazardClass<\/td>\n6.1<\/span><\/td>\n<\/tr>\n
PackingGroup<\/td>\nII<\/span><\/td>\n<\/tr>\n
Hazardous Substances Data<\/td>\n12108-13-3(Hazardous Substances Data)<\/a><\/span><\/td>\n<\/tr>\n
Toxicidade<\/td>\nLD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg\/kg; orally in male, female rats: 175 \u00b133; 89 \u00b114; LC50 inhalation in rat: 0.22 mg\/l (Stara)<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<\/div>","protected":false},"excerpt":{"rendered":"

O metilciclopentadienil tricarbonilo de mangan\u00eas, geralmente referido como Mn2(CO)10 ou simplesmente como \"carbonilo de mangan\u00eas\", \u00e9 um composto organomet\u00e1lico com a f\u00f3rmula molecular C5H5MnO3. Trata-se de um s\u00f3lido cristalino castanho-escuro a preto, altamente sens\u00edvel ao ar e \u00e0 humidade devido \u00e0 sua reatividade.<\/p>\n

Este composto \u00e9 caracterizado pela sua estrutura c\u00edclica, em que um grupo metilo est\u00e1 ligado a um anel ciclopentadienilo que est\u00e1 ligado a um \u00e1tomo de mangan\u00eas. O \u00e1tomo de mangan\u00eas \u00e9 ainda coordenado por tr\u00eas grupos carbonilo, que s\u00e3o essenciais para a estabilidade da mol\u00e9cula.<\/p>\n

O Mn2(CO)10 \u00e9 utilizado em v\u00e1rias aplica\u00e7\u00f5es, incluindo como precursor na s\u00edntese de outros compostos organomet\u00e1licos e na produ\u00e7\u00e3o de especialidades qu\u00edmicas e materiais. \u00c9 tamb\u00e9m utilizado na ind\u00fastria farmac\u00eautica para a s\u00edntese de mol\u00e9culas org\u00e2nicas complexas e como catalisador em certas reac\u00e7\u00f5es qu\u00edmicas.<\/p>\n

O composto \u00e9 conhecido pela sua volatilidade e deve ser manuseado com cuidado numa atmosfera inerte para evitar a decomposi\u00e7\u00e3o. As suas aplica\u00e7\u00f5es industriais s\u00e3o limitadas pela sua toxicidade e pela necessidade de procedimentos de manuseamento especializados.<\/p>\n

Em resumo, o metilciclopentadienil mangan\u00eas tricarbonilo \u00e9 um composto organomet\u00e1lico vers\u00e1til com uma gama de aplica\u00e7\u00f5es na s\u00edntese qu\u00edmica e na ind\u00fastria. A sua estrutura e reatividade \u00fanicas tornam-no um composto valioso mas dif\u00edcil de trabalhar em ambientes cient\u00edficos e industriais.<\/p>","protected":false},"featured_media":196,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"product_brand":[],"product_cat":[18],"product_tag":[19],"class_list":{"0":"post-176","1":"product","2":"type-product","3":"status-publish","4":"has-post-thumbnail","6":"product_cat-petroleum-additives","7":"product_tag-petroleum-additives","9":"first","10":"instock","11":"shipping-taxable","12":"product-type-simple"},"_links":{"self":[{"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/product\/176","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/product"}],"about":[{"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/types\/product"}],"replies":[{"embeddable":true,"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/comments?post=176"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/media\/196"}],"wp:attachment":[{"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/media?parent=176"}],"wp:term":[{"taxonomy":"product_brand","embeddable":true,"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/product_brand?post=176"},{"taxonomy":"product_cat","embeddable":true,"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/product_cat?post=176"},{"taxonomy":"product_tag","embeddable":true,"href":"https:\/\/chemneo.com\/pt\/wp-json\/wp\/v2\/product_tag?post=176"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}